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==[[Molecular dynamics studies of poly(ethylene oxide) based electrolytes]] | ==[[Molecular dynamics studies of poly(ethylene oxide) based electrolytes]] [[Image:PEO small.png]]== | ||
[[Image:PEO small.png]] | |||
Solid electrolytes for the Lithium-Ion Polymer Battery can be produced by mixing a lithium salt, typically LiPF6 or LiBF4, into poly(ethylene oxide) (PEO), -(CH2CH2O)n-. However, such electrolytes only exhibit adequate ionic conductivity (>10-4 S/cm) at temperatures above 70°C, where the polymer becomes amorphous. The conventional wisdom has been that the high degree of local order (“crystallinity”) is the reason for the poor ionic conductivity at ambient temperatures. Much attention has therefore been devoted to the task of increasing the amorphous content of the PEO electrolyte at ambient temperatures. | Solid electrolytes for the Lithium-Ion Polymer Battery can be produced by mixing a lithium salt, typically LiPF6 or LiBF4, into poly(ethylene oxide) (PEO), -(CH2CH2O)n-. However, such electrolytes only exhibit adequate ionic conductivity (>10-4 S/cm) at temperatures above 70°C, where the polymer becomes amorphous. The conventional wisdom has been that the high degree of local order (“crystallinity”) is the reason for the poor ionic conductivity at ambient temperatures. Much attention has therefore been devoted to the task of increasing the amorphous content of the PEO electrolyte at ambient temperatures. | ||
Revision as of 16:16, 9 February 2007
Molecular dynamics studies of poly(ethylene oxide) based electrolytes 
Solid electrolytes for the Lithium-Ion Polymer Battery can be produced by mixing a lithium salt, typically LiPF6 or LiBF4, into poly(ethylene oxide) (PEO), -(CH2CH2O)n-. However, such electrolytes only exhibit adequate ionic conductivity (>10-4 S/cm) at temperatures above 70°C, where the polymer becomes amorphous. The conventional wisdom has been that the high degree of local order (“crystallinity”) is the reason for the poor ionic conductivity at ambient temperatures. Much attention has therefore been devoted to the task of increasing the amorphous content of the PEO electrolyte at ambient temperatures.